Ağırtaş, Mehmet SalihCabir, BeyzaGümüş, SelçukÖzdemir, SadinDündar, Abdurrahman2021-06-112021-06-112018AĞIRTAŞ M. S,CABİR B,GÜMÜŞ S,ÖZDEMİR S,DÜNDAR A (2018). Synthesis and antioxidant, aggregation, and electronic properties of 6-tert-butyl-1,4-benzodioxine substituted phthalocyanines. Turkish Journal of Chemistry, 42(1), 100 - 111.1300-05271303-6130https://app.trdizin.gov.tr/makale/TWpVMU5qWXlNZz09/synthesis-and-antioxidant-aggregation-and-electronic-properties-of-6-tert-butyl-1-4-benzodioxine-substituted-phthalocyanineshttps://hdl.handle.net/20.500.12514/2525As a starting material, 7-tert-butyldibenzo [b,e] [1,4] dioxine-2,3-dicarbonitrile was prepared by the reac- tion of 4-tert-butylcatechol with 4,5-dichlorophthalonitrile. Metallophthalocyanine complexes ( 4 { 7 ) were obtained by cyclotetramerization of 7-tert-butyldibenzo [b,e] [1,4] dioxine-2,3-dicarbonitrile. All compounds were characterized by elemental analysis and other spectroscopic methods (IR, UV/Vis, and 1 H NMR). Phthalocyanine compounds remained nonaggregated in tetrahydrofuran at the studied concentration ranges. Metallophthalocyanines ( 4 { 7 ) were tested for their antioxidant activities. The antioxidant activity processes included evaluation of radical-scavenging activity, chelat- ing activity, and reducing power. These compounds were compared to standard antioxidant ascorbic acid. The electronic data of the new compounds were obtained by computational calculations at the B3LYP/6-31G (d,p) level of theory.en10.3906/kim-1605-59info:eu-repo/semantics/openAccessPhthalocyanines, synthesis, aggregation, antioxidant, electronic propertiesArticle421100111Q3Q3WOS:0004261594000092-s2.0-85041898756255662