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    Basic Red 18 and Remazol Brilliant Blue R biosorption using Russula brevipes, Agaricus augustus, Fomes fomentarius
    (Water Practice and Technology, 2022) Arslantaş, Ceren; M’barek, Islem; Saleh, Mohammed; Isik, Zelal; Ozdemire, Sadin; Dündar, Abdurrahman; Dizge, Nadir
    In this study, the adsorption abilities of Russula brevipes (RB), Agaricus augustus (AA), and Fomes fomentarius (FF) were evaluated in Basic Red 18 (BR18) and Remazol Brilliant Blue R (RBBR) biosorption from textile effluent. The adsorbents were characterized via Scanning Electron Microscopy (SEM), Energy Dispersive Spectrometer (SEM-EDS), and Fourier transform infrared spectroscopy (FT/IR). Fomes fomentarius presented a low sorption capacity contrary to the two other fungi (RB and AA). RB and AA were selected as potential adsorbents for BR18 and RBBR, respectively. The maximum BR18 removal efficiencies for 10, 25, and 50 mg/L were obtained after 60 min to be 90, 88, and 86%, respectively. The RBBR adsorption efficiencies were 96.4, 96, and 90% for dye concentrations of 10, 25, and 50 mg/L. The adsorption of BR18 onto the RB biomass followed the Freundlich isotherm, while Langmuir is the best isotherm for RBBR sorption’s elucidation onto AA fungus biomass. The removal of BR18 by BR biomass was found to follow the pseudo-second order. In contrast, the adsorption of RBBR onto the AA biomass followed Lagergren’s pseudo-first order. For both adsorbents, the adsorption was exothermic, feasible, and spontaneous in nature. Finally, the dyes’ biosorption process was perfectly achieved onto fungi biomass via physisorption
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    Preconcentrations of Pb(II), Ni(II) and Zn(II) by solid phase bio-extractor using thermophilic Bacillus subtilis loaded multiwalled carbon nanotube biosorbent
    (ScienceDirect, 2023) Ozdemir, Sadin; Dündar, Abdurrahman; Dizge, Nadir; Kılınç, Ersin; Balakrishnan, Deepanraj; Prasad, Kashi Sai; Senthilkumar, Natarajan
    An alternative biotechnological solid phase bio-extraction (SPE) method was developed. Bacillus subtilis loaded multiwalled carbon nanotube was designed and used as biosorbent for the preconcentrations of Pb(II), Ni(II), and Zn(II). The experimental parameters such as sample flow rate, pH of sample solution, amounts of Bacillus subtilis and multiwalled carbon nanotube, volume of sample solution and reusability of column which affects the analytical characteristics of the SPE method were investigated in details. Surface structures were investigated by using FTIR, SEM. The best pH was determined as 5.0 and the percentages recoveries of Zn(II), Ni(II), and Pb(II) were determined as 99.1%, 98.7%, and 96.2%, respectively, at a flow rate of 3 mL/min. In this study, in which the profitable sample volume was determined as 400 mL and the amount of multiwalled carbon nanotube (MWCNT) as 50 mg. It was also observed that the column had a significant potential to preconcentrate Zn(II), Ni(II), and Pb(II) even after 25 reuses. The biosorption capacities for Pb(II), Ni(II) and Zn(II) were calculated as 34.2 mg/g, 36.8 mg/g and 45.5 mg/g respectively. The LOD values were calculated as 0.024 ng/mL for Pb(II), 0.029 ng/mL for Ni(II), and 0.019 ng/mL for Zn(II). The linear range was detected as 0.25–25 ng/mL. The concentrations of Pb(II), Ni(II), and Zn(II) in a variety of real food samples were determined by using developed method after application of certified reference sample.