Different peripheral substituted phthalocyanines: Synthesis, characterization, aggregation behavior, antioxidant and antibacterial activity

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dc.authoridCELEBI, METIN -- 0000-0003-1475-8878en_US
dc.contributor.authorCelebi, M.
dc.contributor.authorAgirtas, M. S.
dc.contributor.authorDundar, A.
dc.date.accessioned14.07.201910:50:10
dc.date.accessioned2019-07-16T20:44:02Z
dc.date.available14.07.201910:50:10
dc.date.available2019-07-16T20:44:02Z
dc.date.issued2015
dc.department[Belirlenecek]en_US
dc.description.abstractIn this study, a novel phthalonitrile, 4-chloro-5-(2-((2-hydroxyethyl)(p-tolyl)amino)ethoxy)phthalonitrile (3), and its metallophthalocyanine derivatives (4-6) are prepared by cyclotetramerization with appropriate metal salts in dimethylformamide. The newly prepared compounds have been characterized by several spectroscopic techniques. All compounds are evaluated for their antioxidant and antibacterial potential. For the antioxidant studies, three tests are applied; DPPH (2,2-diphenyl-1-picrylhydrazylradical) scavenging, metal chelating and reducing power activity. Compound 4 exhibits the best DPPH scavenging activity as 35.2% at 100 mg/L concentration. The metal chelating activities of compounds 3 and 4 are 69.7% and 56.4%, respectively. Reducing power activities of compounds 3 and 4 are higher than alpha-tocopherol which is used as positive control. All compounds show moderate antibacterial activity when compared to the standard antibiotics, amikacin and tetracycline.en_US
dc.description.sponsorshipYuzuncu Yil University [2013-FBE-D059]en_US
dc.description.sponsorshipThis study was supported by the Research Fund of Yuzuncu Yil University (2013-FBE-D059).en_US
dc.identifier.doi10.1134/S0022476615080284en_US
dc.identifier.endpage1645en_US
dc.identifier.issn0022-4766
dc.identifier.issn1573-8779
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-84961371076en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage1638en_US
dc.identifier.urihttps://dx.doi.org/10.1134/S0022476615080284
dc.identifier.urihttps://hdl.handle.net/20.500.12514/1356
dc.identifier.volume56en_US
dc.identifier.wosWOS:000369060800028en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPLEIADES PUBLISHING INCen_US
dc.relation.ispartofJOURNAL OF STRUCTURAL CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectsynthesisen_US
dc.subjectmetalen_US
dc.subjectphthalocyaninesen_US
dc.subjectaggregationen_US
dc.subjectantioxidanten_US
dc.subjectantibacterial activityen_US
dc.titleDifferent peripheral substituted phthalocyanines: Synthesis, characterization, aggregation behavior, antioxidant and antibacterial activityen_US
dc.typeArticleen_US

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