Metallo Phthalocyanines bearing 2-Isopropyl-6-methylpyrimidin-4-yloxy Substituents: Synthesis, Characterization, Aggregation Behavior, Antioxidant and Antibacterial Activity, and Electronic Properties

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dc.contributor.authorAgirtas, M. Salih
dc.contributor.authorDede, Emrah
dc.contributor.authorGumus, Selcuk
dc.contributor.authorDundar, Abdurrahman
dc.contributor.authorOkumus, Veysi
dc.date.accessioned14.07.201910:50:10
dc.date.accessioned2019-07-16T20:44:07Z
dc.date.available14.07.201910:50:10
dc.date.available2019-07-16T20:44:07Z
dc.date.issued2014
dc.department[Belirlenecek]en_US
dc.description.abstractA novel phthalonitrile derivative bearing 2-isopropyl-6-methylpyrimidin-4-yloxy substituents at peripheral positions was synthesized by a nucleophilic substitution reaction. Metallophthalocyanines were obtained from the reaction of the novel phthalonitrile with metal Zn, Cu, Co, and Ni salts. The characterization of the compounds was performed using elemental analysis as well as UV/Vis, FT-IR, and H-1-NMR spectroscopy. The aggregation behaviors of phthalocyanine complexes were also investigated. These metallophthalocyanines do not show any aggregation behavior between 10 (4)-10 (6) M concentration range in THF. The antioxidant activities of the synthesized compounds were evaluated using three different tests: 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging, metal chelating activity, and reducing power assays. All the compounds exhibited various antioxidant activities. In addition, antimicrobial activity of the compounds was tested over four gram positive and two gram negative bacteria. Moreover, the ground-state geometries of the complexes were optimized using density functional theory (DFT) methods at B3LYP/6-31G(d,p) level in order to obtain information about the 3D arrangements and electronic structure.en_US
dc.identifier.doi10.1002/zaac.201400129en_US
dc.identifier.endpage1959en_US
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-85117547797en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1953en_US
dc.identifier.urihttps://dx.doi.org/10.1002/zaac.201400129
dc.identifier.urihttps://hdl.handle.net/20.500.12514/1402
dc.identifier.volume640en_US
dc.identifier.wosWOS:000340900200015en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.relation.ispartofZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIEen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhthalocyaninesen_US
dc.subjectCharacterizationen_US
dc.subjectAggregationen_US
dc.subjectAntioxidant activityen_US
dc.subjectAntibacterial activityen_US
dc.subjectElectronic structureen_US
dc.titleMetallo Phthalocyanines bearing 2-Isopropyl-6-methylpyrimidin-4-yloxy Substituents: Synthesis, Characterization, Aggregation Behavior, Antioxidant and Antibacterial Activity, and Electronic Propertiesen_US
dc.typeArticleen_US

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