Metallo and metal free phthalocyanines bearing (4-(1(4-phenoxyphenyl)-1-phenylethyl)phenol substituents: Synthesis, characterization, aggregation behavior, electronic, antioxidant and antibacterial properties

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dc.contributor.authorAgirtas, M. Salih
dc.contributor.authorGuven, M. Emin
dc.contributor.authorGumus, Selcuk
dc.contributor.authorOzdemir, Sadin
dc.contributor.authorDundar, Abdurrahman
dc.date.accessioned14.07.201910:50:10
dc.date.accessioned2019-07-16T20:44:07Z
dc.date.available14.07.201910:50:10
dc.date.available2019-07-16T20:44:07Z
dc.date.issued2014
dc.departmentMAÜ, Meslek Yüksekokulları, Sağlık Hizmetleri Meslek Yüksekokulu, Tıbbi Hizmetler ve Teknikler Bölümüen_US
dc.description.abstractAs starting material the phthalonitrile derivative bearing (4-(1(4-phenoxyphenyl)-1-phenylethyl)phenol substituents at peripheral position was prepared by a nucleophilic displacement reaction. Cyclotetramerization of 4-(4-(1-(4-hydroxyyphenyl)-1-phenylethyl)phenoxy)phthalonitrile derivative in the presence of corresponding metal salts gave the new metallophthalocyanines. Metal free phthalocyanine was obtained from the reaction of 4-(4-(1-(4-hydroxyyphenyl)-1-phenylethyl)phenoxy)phthalonitrile units. The novel compounds have been characterized by using various spectroscopic data. The aggregation investigations carried out in different concentrations indicate that 4-(4-(1-(4-hydroxyyphenyl)-1-phenylethyl)phenoxy)phthalocyanine compounds do not have any aggregation behavior for the concentration range of 10(-4)-10(-5) M in tetrahydrofuran. The antioxidant activities of novel compounds were analyzed through radical scavenging ability of 1,1-dipheny1-2-picrylhydrazyl, chelating ability to ferrous ions and reducing power. In addition to these, the antibacterial activities of compounds were investigated. Moreover, the ground-state geometries of the complexes were optimized using B3LYP/6-31G(d,p) level of density functional theory in order to predict the three-dimensional geometries and electronic structure. (C) 2014 Elsevier B.V. All rights reserved.en_US
dc.identifier.citationAğırtaş, M. S., Güven, M. E., Gümüş, S., Özdemir, S., & Dündar, A. (2014). Metallo and metal free phthalocyanines bearing (4-(1(4-phenoxyphenyl)-1-phenylethyl)phenol substituents: Synthesis, characterization, aggregation behavior, electronic, antioxidant and antibacterial properties. Synthetic Metals, 195, 177–184. https://doi.org/10.1016/j.synthmet.2014.06.004
dc.identifier.doi10.1016/j.synthmet.2014.06.004en_US
dc.identifier.endpage184en_US
dc.identifier.issn0379-6779
dc.identifier.scopus2-s2.0-84903316908en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage177en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.synthmet.2014.06.004
dc.identifier.urihttps://hdl.handle.net/20.500.12514/1399
dc.identifier.volume195en_US
dc.identifier.wosWOS:000341469300026en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE SAen_US
dc.relation.ispartofSYNTHETIC METALSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSynthesisen_US
dc.subjectPhthalocyaninesen_US
dc.subjectAggregationen_US
dc.subjectAntioxidanten_US
dc.subjectAntibacterialen_US
dc.subjectElectronic structureen_US
dc.titleMetallo and metal free phthalocyanines bearing (4-(1(4-phenoxyphenyl)-1-phenylethyl)phenol substituents: Synthesis, characterization, aggregation behavior, electronic, antioxidant and antibacterial propertiesen_US
dc.typeArticleen_US

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