Synthesis of novel magnetic nano-sorbent functionalized with N-methyl-D-glucamine by click chemistry and removal of boron with magnetic separation method

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dc.contributor.authorTural, Servet
dc.contributor.authorEce, Mehmet Sakir
dc.contributor.authorTural, Bilsen
dc.date.accessioned14.07.201910:50:10
dc.date.accessioned2019-07-16T20:43:52Z
dc.date.available14.07.201910:50:10
dc.date.available2019-07-16T20:43:52Z
dc.date.issued2018
dc.departmentMAÜ, Meslek Yüksekokulları, Sağlık Hizmetleri Meslek Yüksekokulu, Tıbbi Hizmetler ve Teknikler Bölümüen_US
dc.description.abstractClick chemistry refers to a group of reactions that are fast, simple to use, easy to purify, versatile, regiospecific, and give high product yields. Therefore, a novel, efficient magnetic nano-sorbent based on N-methyl-D-glucamine attached to magnetic nanoparticles was prepared using click coupling method. Its boron sorption capacity was compared with N-methyl-D-glucamine direct attached nano-sorbent. The characterization of the magnetic sorbents was investigated by several techniques such as X-ray diffraction, scanning electron microscope, transmission electron microscope, dynamic light scattering, thermogravimetric analysis, Fourier transform infrared spectrophotometer, and vibrating sample magnetometer. The boron sorption capacity of sorbents was compared by studying various essential factors influencing the sorption, like sorbate concentration, sorbents dosage, pH of the solution, and contact time. Langmuir and Freundlich and Dubinin-Radushkevich adsorption isotherms models were applied. Percent removal and sorption capacities efficiencies of sorbents obtained with direct and click coupling are found to be 49.5%, 98.7% and 6.68 mg/g, 13.44 mg/g respectively. Both sorbents have been found to be compatible with Langmuir isotherm, and the boron sorption kinetics conforms to the pseudo second order kinetics. The reusability study of sorbents was carried out five times for boron sorption and desorption.en_US
dc.description.sponsorshipDicle University Research Fund (DUBAP) [13-ZEF-28, ZGEF.16.008]en_US
dc.description.sponsorshipThis project is funded by the financial support from Dicle University Research Fund (DUBAP, Project No. 13-ZEF-28, DUBAP, Project No. ZGEF.16.008).en_US
dc.identifier.citationTural, S., Ece, M. Ş., & Tural, B. (2018). Synthesis of novel magnetic nano-sorbent functionalized with N-methyl-D-glucamine by click chemistry and removal of boron with magnetic separation method. Ecotoxicology and Environmental Safety, 162, 245–252. https://doi.org/10.1016/j.ecoenv.2018.06.066
dc.identifier.doi10.1016/j.ecoenv.2018.06.066en_US
dc.identifier.endpage252en_US
dc.identifier.issn0147-6513
dc.identifier.issn1090-2414
dc.identifier.pmid29990737en_US
dc.identifier.scopus2-s2.0-85049444571en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage245en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.ecoenv.2018.06.066
dc.identifier.urihttps://hdl.handle.net/20.500.12514/1247
dc.identifier.volume162en_US
dc.identifier.wosWOS:000440879500030en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherACADEMIC PRESS INC ELSEVIER SCIENCEen_US
dc.relation.ispartofECOTOXICOLOGY AND ENVIRONMENTAL SAFETYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBoronen_US
dc.subjectClick chemistryen_US
dc.subjectMagnetic separation methoden_US
dc.subjectNano-sorbenten_US
dc.subjectSorptionen_US
dc.titleSynthesis of novel magnetic nano-sorbent functionalized with N-methyl-D-glucamine by click chemistry and removal of boron with magnetic separation methoden_US
dc.typeArticleen_US

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