Facile synthesis and comprehensive characterization of Ni-decorated amine groups-immobilized Fe3O4@SiO2 magnetic nanoparticles having enhanced solar cell efficiency

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dc.contributor.authorEce, Mehmet Şakir
dc.contributor.authorEkinci, Arzu
dc.contributor.authorKutluay, Sinan
dc.contributor.authorŞahin, Ömer
dc.contributor.authorHoroz, Sabit
dc.date.accessioned2021-07-28T07:47:02Z
dc.date.available2021-07-28T07:47:02Z
dc.date.issued2021en_US
dc.departmentMAÜ, Meslek Yüksekokulları, Sağlık Hizmetleri Meslek Yüksekokulu, Tıbbi Hizmetler ve Teknikler Bölümüen_US
dc.description.abstractIn this study, the synthesis and comprehensive characterization of Fe3O4@SiO2 magnetic nanoparticles (MNPs) immobilized with L-Arginine decorated with nickel (Ni) was achieved, and their ability in solar cell efficiency was evaluated. Fe3O4, Fe3O4@SiO2, Fe3O4@SiO2@L-Arginine and Fe3O4@SiO2@L-Arginine-Ni MNPs were prepared by co-precipitation and sol-gel methods. The structural, morphological, optical and textural properties of the prepared MNPs were clarified by Fourier Transform Infrared Spectroscopy (FTIR), Energy-Dispersive X-Ray (EDX), X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Brunauer–Emmett–Teller (BET), Thermal Gravimetric Analysis (TGA) and Ultraviolet-Visible (UV-Vis) analyzes. From the BET data, it is understood that the specific surface area of the prepared Fe3O4, Fe3O4@SiO2 and Fe3O4@SiO2@L–Arginine MNPs is 60.85, 28.99 and 29.84 m2/g, respectively. From the pore size distribution determined by Barrett-Joyner-Halenda (BJH) method, it was understood that the pore radius of Fe3O4, Fe3O4@SiO2 and Fe3O4@SiO2@L–Arginine MNPs were in the range of mesopore and the average pore radius was equal to approximately 11.03, 9.11 and 28.45 nm, respectively. It is assumed that the half pore widths calculated by the density functional theory (DFT) method of the prepared of Fe3O4, Fe3O4@SiO2 and Fe3O4@SiO2@L-Arginine MNPs are 5.58, ∼ 0.88, and ∼ 17.98 nm, respectively. The energy band gap of the prepared MNPs with spinel structure was determined as approximately 3.10 eV. In addition to the structural, morphological, optical and textural properties, the photovoltaic properties of the prepared MNPs were examined. Au/CuO/Fe3O4@SiO2@L–Arginine-Ni/ZnO/SnO2:F solar cell device was created by using existing Fe3O4@SiO2@L–Arginine-Ni MNPs as buffer layer. The power conversion efficiency (%) of the prepared Fe3O4@SiO2@L–Arginine-Ni MNPs based solar cell device was calculated as 1.84 %. This numerical result shows that the prepared Fe3O4@SiO2@L-Arginine-Ni MNPs can be used as a promising buffer layer in a solar structure.en_US
dc.description.sponsorshipThis project is funded by the financial support from Mardin Artuklu University (Project No. MAU.BAP.18.SHMYO.030).en_US
dc.identifier.citationEce, M. Ş., Ekinci, A., Kutluay, S., Şahin, Ö., & Horoz, S. (2021). Facile synthesis and comprehensive characterization of Ni-decorated amine groups-immobilized Fe3O4@SiO2 magnetic nanoparticles having enhanced solar cell efficiency. In Journal of Materials Science: Materials in Electronics (Vol. 32, Issue 13, pp. 18192–18204). Springer Science and Business Media LLC. https://doi.org/10.1007/s10854-021-06361-z
dc.identifier.scopus2-s2.0-85107738919en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85107738919&doi=10.1007%2fs10854-021-06361-z&origin=inward&txGid=7073f64120f50db0ebf25de7c4bb5047
dc.identifier.urihttps://hdl.handle.net/20.500.12514/2705
dc.identifier.urihttps://doi.org/10.1007/s10854-021-06361-z
dc.identifier.urihttps://www.webofscience.com/wos/woscc/full-record/WOS:000660823400009?AlertId=d383397b-4355-449e-9419-70f9e0e77c15&SID=F62lurvzvUoMJrDI6Mq
dc.identifier.wosWOS:000660823400009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJournal of Materials Science: Materials in Electronicsen_US
dc.relation.ispartofJournal of Materials Science: Materials in Electronicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleFacile synthesis and comprehensive characterization of Ni-decorated amine groups-immobilized Fe3O4@SiO2 magnetic nanoparticles having enhanced solar cell efficiencyen_US
dc.typeArticleen_US

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