Application of Half-Sandwich Metal-Phosphinite Compounds to Biological Activities: Determine the energies of the HOMO and LUMO levels

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dc.contributor.authorMeriç, Nermin
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorZazybin, Alexey
dc.contributor.authorGüzel, Remziye
dc.contributor.authorKayan, Cezmi
dc.contributor.authorKarakaş, Duygu Elma
dc.contributor.authorDündar, Abdurrahman
dc.contributor.authorISLAM, Sholpan
dc.contributor.authorOkumuş, Veysi
dc.contributor.authorAydemir, Murat
dc.date.accessioned2023-01-17T07:16:57Z
dc.date.available2023-01-17T07:16:57Z
dc.date.issued2022en_US
dc.departmentMAÜ, Meslek Yüksekokulları, Sağlık Hizmetleri Meslek Yüksekokulu, Tıbbi Hizmetler ve Teknikler Bölümüen_US
dc.description.abstractMononuclear transition metal complexes 1-(furan-2-yl)ethyldiphenyl[dichloro(η6-p-cymene)ruthenium(II)]phosphinite, (2), 1-(furan-2-yl)ethyldiphenyl[dichloro(η6-benzene) ruthenium(II)] phosphinite (3), 1-(furan-2-yl)ethyldipheny[chloro(η4-1,5-cyclooctadiene)rhodium(I)]phosphinite (4), 1-(furan-2-yl)ethyldiphenyl[dichloro (η5pentamethylcyclopentadienyl)iridium (III)] phosphinite (5) were synthesized and characterized by microanalysis, infrared, MS, and NMR spectroscopy. The biological activities of the complexes were also tested. Compounds 2 and 5 were the best complexes at DPPH radical scavenging and reducing power activity at 73.27 % and 0.41 at 200 μg/mL, respectively. The highest antimicrobial activity exhibited by complex 3 as 14 mm inhibition zone against S. aureus. All of the complexes have cleaved the DNA from the double-strand and exhibited three bands on gel electrophoresis. Moreover, cyclic voltammetry studies of the phosphinite complexes were carried out to determine the energies of the HOMO and LUMO levels as well as to estimate their electrochemical and some electronic properties.en_US
dc.identifier.citationMeriç, N., Rafikova, K., Zazybin, A., Güzel, R., Kayan, C., Elma Karakaş, D., ... & Aydemir, M. (2022). Application of Half‐Sandwich Metal‐Phosphinite Compounds to Biological Activities: Determine the energies of the HOMO and LUMO levels. Zeitschrift für anorganische und allgemeine Chemie, e202200126.en_US
dc.identifier.doi10.1002/zaac.202200126en_US
dc.identifier.scopus2-s2.0-85142272576en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.urihttps://doi.org/10.1002/zaac.202200126
dc.identifier.urihttps://www.scopus.com/record/display.uri?eid=2-s2.0-85142272576&origin=SingleRecordEmailAlert&dgcid=raven_sc_affil_en_us_email&txGid=dcdf2378a185e191548c63c33559e7d9
dc.identifier.urihttps://hdl.handle.net/20.500.12514/3329
dc.identifier.wosWOS:000888397300001en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley Online Libraryen_US
dc.relation.ispartofZeitschrift fur Anorganische und Allgemeine Chemieen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBiological Study; Electron transport; Phosphinite Ligand; Transition metalen_US
dc.titleApplication of Half-Sandwich Metal-Phosphinite Compounds to Biological Activities: Determine the energies of the HOMO and LUMO levelsen_US
dc.typeArticleen_US

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